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| Staff Scientist |
| NAME |
Valentin Iota |
| PHONE |
(925)424-3354 |
| FAX |
(925)422-5940 |
| E-MAIL |
Iota1@llnl.gov |
| ADDRESS |
Lawrence Livermore National Lab
7000 East Avenue, L-415
Livermore, CA 94550 |
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I joined the High Pressure Group at LLNL
in 1998, after getting my Ph.D. in Physics from University
at Buffalo –SUNY. Since then, I have been involved in
materials research at high pressure (diamond anvil cell) using
a wide rage of experimental probes from optical measurements
to x-ray diffraction and spectroscopy.
My current research explores the physics and chemistry of
materials over a broad range of pressure-temperature conditions,
with emphasis on the relationship between structural phase
stability, chemical bonding, and electronic structure in highly
compressed systems.
One area of particular interest involves the bonding changes
of molecular solids under extreme thermodynamic conditions.
The morphology and mechanical properties of molecular systems
are largely controlled by the large disparity between strong
intra-molecular bonds and relatively weak inter-molecular
cohesive forces. In highly compressed molecular systems, however,
this intra/inter molecular bonding hierarchy becomes less
differentiated, and the materials eventually transform to
covalent, ionic or metallic solids. One example is that of
carbon dioxide undergoing a sequence of bonding changes with
pressure from a simple molecular solid to a series of highly
interacting (associated) phases and eventually to a fully
covalent, tetrahedrally coordinated solid.
A second area of interest has been the complex relationship
between atomic structure and electronic properties in magnetic
transition metals at pressures reaching Earth Core conditions.
Beyond its applications to Geomagnetism and Planetary Physics,
this research advances our fundamental understanding of spin
polarization and ordered magnetism in itinerant electron systems.
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C. S. Yoo, B. Maddox, J. -H. P. Klepeis, V. Iota, W. Evans,
A. McMahan, M. Hu, P. Chow, M. Somayazulu, D. Hausermann, R.
T. Scalettar, and W. E. Pickett, "First-order Isostructural
Mott transition in highly compressed MnO", Phys. Rev.
Lett. 94(11), 115502 (2005) [pdf]
Sang-Heon Shim, Thomas S. Duffy, Raymond Jeanloz, Choong-Shik
Yoo, and Valentin Iota, "Raman spectroscopy and x-ray diffraction
of phase transitions in Cr2O3 to 61 GPa", Phys. Rev.
B 69, 144107 (2004) [pdf]
Crystal Structure of Bent Carbon Dioxide Phase IV; J.-H. Park,
C.S. Yoo, V. Iota, H. Cynn, M.F. Nicol and T. LeBihan, Phys.
Rev. B. 68, 014107 (2003) [pdf]
B. Baer, H. Cynn, V. Iota, C. S. Yoo, G. Shen, "Phase Diagram
and Equation of State of Praseodymium at High Pressures and
Temperatures", Phys. Rev. B 67,
134115 (2003) [pdf]
Crystal structure of pseudo-six-fold carbon dioxide phase II
at high pressures and temperatures, C. S. Yoo, H. Kohlmann,
H. Cynn, M. F. Nicol, V. Iota, and T. LeBihan; Phys. Rev.
B 65, 104103 (2002) [pdf]
Phase Diagram of Carbon Dioxide: Evidence for an Associated
Phase; V. Iota and C-S. Yoo, Phys. Rev. Lett. 86,
5922 (2001) [pdf]
Quartz-like CO2: an optically nonlinear extended solid at high
pressures and temperatures; V. Iota, C. S. Yoo, H. Cynn, Science
283, 1510 (1999) [pdf] |
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