High Pressure Physics Group
 
 
 
 
 
 
Valentin Iota
Staff Scientist
NAME Valentin Iota
PHONE (925)424-3354
FAX (925)422-5940
E-MAIL Iota1@llnl.gov
ADDRESS Lawrence Livermore National Lab
7000 East Avenue, L-415
Livermore, CA 94550
Biography

I joined the High Pressure Group at LLNL in 1998, after getting my Ph.D. in Physics from University at Buffalo –SUNY. Since then, I have been involved in materials research at high pressure (diamond anvil cell) using a wide rage of experimental probes from optical measurements to x-ray diffraction and spectroscopy.

My current research explores the physics and chemistry of materials over a broad range of pressure-temperature conditions, with emphasis on the relationship between structural phase stability, chemical bonding, and electronic structure in highly compressed systems.

One area of particular interest involves the bonding changes of molecular solids under extreme thermodynamic conditions. The morphology and mechanical properties of molecular systems are largely controlled by the large disparity between strong intra-molecular bonds and relatively weak inter-molecular cohesive forces. In highly compressed molecular systems, however, this intra/inter molecular bonding hierarchy becomes less differentiated, and the materials eventually transform to covalent, ionic or metallic solids. One example is that of carbon dioxide undergoing a sequence of bonding changes with pressure from a simple molecular solid to a series of highly interacting (associated) phases and eventually to a fully covalent, tetrahedrally coordinated solid.

A second area of interest has been the complex relationship between atomic structure and electronic properties in magnetic transition metals at pressures reaching Earth Core conditions. Beyond its applications to Geomagnetism and Planetary Physics, this research advances our fundamental understanding of spin polarization and ordered magnetism in itinerant electron systems.

Selected Publications
C. S. Yoo, B. Maddox, J. -H. P. Klepeis, V. Iota, W. Evans, A. McMahan, M. Hu, P. Chow, M. Somayazulu, D. Hausermann, R. T. Scalettar, and W. E. Pickett, "First-order Isostructural Mott transition in highly compressed MnO", Phys. Rev. Lett. 94(11), 115502 (2005) [pdf]

Sang-Heon Shim, Thomas S. Duffy, Raymond Jeanloz, Choong-Shik Yoo, and Valentin Iota, "Raman spectroscopy and x-ray diffraction of phase transitions in Cr2O3 to 61 GPa", Phys. Rev. B 69, 144107 (2004) [pdf]

Crystal Structure of Bent Carbon Dioxide Phase IV; J.-H. Park, C.S. Yoo, V. Iota, H. Cynn, M.F. Nicol and T. LeBihan, Phys. Rev. B. 68, 014107 (2003) [pdf]

B. Baer, H. Cynn, V. Iota, C. S. Yoo, G. Shen, "Phase Diagram and Equation of State of Praseodymium at High Pressures and Temperatures", Phys. Rev. B 67, 134115 (2003) [pdf]

Crystal structure of pseudo-six-fold carbon dioxide phase II at high pressures and temperatures, C. S. Yoo, H. Kohlmann, H. Cynn, M. F. Nicol, V. Iota, and T. LeBihan; Phys. Rev. B 65, 104103 (2002) [pdf]

Phase Diagram of Carbon Dioxide: Evidence for an Associated Phase; V. Iota and C-S. Yoo, Phys. Rev. Lett. 86, 5922 (2001) [pdf]

Quartz-like CO2: an optically nonlinear extended solid at high pressures and temperatures; V. Iota, C. S. Yoo, H. Cynn, Science 283, 1510 (1999) [pdf]
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